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Azosubstituierte Porphyrine
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Kerstin Ldtke-Buzug fhrt in die vielfltigen Anwendungs- und Einsatzmglichkeiten fr Porphyrine im medizinischen und naturwissenschaftlich-technischen Bereich ein und stellt Synthesevorschriften sowie Analysemethoden von Azobenzolsubstituierten Porphyrinsystemen vor, welche in fast allen biologischen Systemen vorkommen. Dazu synthetisiert sie eine Reihe von azobenzolsubstituierten Mono- und Diporphyrinen und untersucht sie eingehend spektroskopisch und elektrochemisch. Sie weist den Einfluss unterschiedlicher Azobenzolsubstituenten auf die Redoxeigenschaften und die spektroskopischen Eigenschaften der Porphyringruppen eindeutig nach und quantifiziert ihn mit Hilfe von Hammett-Parametern.
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