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Titangruppe: Elemente der vierten Nebengruppe

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Springer Nature
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9783658126391
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Hermann Sicius beschreibt die Eigenschaften und Eigenheiten der Elemente der vierten Nebengruppe (Titangruppe). Die Entdeckung des Titans und des Zirkoniums erfolgte zu Beginn des 19. Jahrhunderts, die des Hafniums erst mehr als hundert Jahre spter. Atomkerne des Rutherfordiums wurden erstmals 1964 durch Kernfusion erzeugt. Vom Titan zum Hafnium nehmen Dichte, Schmelzpunkte und -wrmen sowie Siedepunkte und Verdampfungswrmen zu. Die Elemente dieser Gruppe sind teils reaktiv, teils aber auch erstaunlich passiv. An der Luft schtzt sie eine passivierende Oxidschicht vor weiterer Korrosion und auch in Suren sind sie nur vereinzelt lslich. Mit vielen Nichtmetallen reagieren sie aber bei erhhter bzw. hoher Temperatur. Titan-IV-oxid reagiert amphoter, die Dioxide des Zirkoniums und Hafniums schwach basisch.

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