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Cer-katalysierte, oxidative C-C-Kupplungsreaktionen

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Brand
Springer Nature
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N/A
Part Number
0
GTIN
9783658128029
Condition
New
Product Description

Irina Geibel zeigt eine innovative Anwendungsmglichkeit des preiswerten und kologisch unbedenklichen Seltenerdmetallsalzes CeCl3 7 H2O bei der Knpfung von C-C-Bindungen mit Luftsauerstoff als Oxidationsmittel auf. Ziel der Arbeit ist die Entwicklung einer neuen atomkonomischen, umwelt- und ressourcenschonenden Eintopfsynthese zur Darstellung von 1,4 Diketonen. In GC-kontrollierten Anstzen werden fr eine Beispielreaktion zahlreiche Reaktionsparameter variiert und dokumentiert. Unter Anwendung der optimierten Reaktionsbedingungen werden 1,4-Diketone hergestellt, die abschlieend als Ausgangsverbindungen in Anellierungsreaktionen eingesetzt werden.

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