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Neuartige Ylidinkomplexe des Niobs

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Brand
Springer Nature
Manufacturer
N/A
Part Number
0
GTIN
9783658128135
Condition
New
Product Description

David Hoffmann stellt die Synthese der ersten Niobtetrelylidinkomplexe des Germaniums und Zinns durch effiziente Salzmetathesereaktion vor. Beide Verbindungen wurden vom Autor IR- und MultikernNMRspektroskopisch charakterisiert und ihre Moleklstruktur im Festkrper durch Rntgenstrahlenbeugung am Einkristall aufgeklrt und diskutiert. Beide Strukturen weisen einen sehr kurzen Tetrel-Niob-Bindungsabstand und ein fast linear koordiniertes Tetrelatom auf. Die Reaktivitt des Niobgermylidinkomplexes gegenber kleinen polaren Moleklen wurde anhand der Reaktionen mit Methanol und Wasser geprft und die Redoxeigenschaften mittels cyclovoltammetrischer Messungen untersucht.

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