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Katalytische Metathese von Alkinen
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Henrike Ehrhorn stellt ber die Low-Oxidation-State-Route mehrere neue Molybdn-Alkylidin-Komplexe her. Die Autorin charakterisiert und diskutiert die Katalysatoren und Zwischenstufen NMR-spektroskopisch und mittels Rntgenstrahlbeugung am Einkristall. Auerdem untersucht sie die Aktivitt der Molybdn-Komplexe in katalytischen Studien gegenber terminalen und internen Alkinen. Hierbei weist Ehrhorn nach, dass der Triisopropylbenzylidin-Komplex eine gute Aktivitt gegenber terminalen Alkinen zeigt und der Perfluoro-tert-butanolat-haltige Molybdn-Komplex eine ungewhnliche Reaktivitt gegenber konjugierten Diinen aufweist.
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