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Untersuchungen ber Reaktionen in flssigem Ammoniak

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Brand
Springer Nature
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N/A
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GTIN
9783663044161
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Product Description

Flssiges Ammoniak ist ein Medium, das dem Wasser in seinen Eigenschaften weitgehend analog ist. Insbesondere ist es in der Lage, wie Wasser eine groe Anzahl von Elektrolyten zu lsen, wobei eine Dissoziation in Ionen erfolgt. Ferner besitzt flssiges Ammoniak eine Eigendissoziation ( 1 ) die der des Wassers an die Seite zu stellen ist: (2) Bedingt wird diese Eigendissoziation durch die amphiproten Eigenschaften des Ammoniaks bzw. Wassers d. h. die Fhigkeit, sowohl H+ bei Gegenwart eines Protonenacceptors unter Bildung von NH bzw. OH- abzudissoziieren 2 als auch infolge Vorhandenseins eines einsamen Elektronenpaares H+ unter Bildung von NH + bzw. H 0+ zu addieren. Man erkennt durch Gegenberstel 4 3 lung von (1) und (2), da NH + dem H 0+ und NH - dem OH- entspricht. Im 3 2 4 "Ammonosystem" ist also NH + das sureanaloge Kation und NH - das basen 2 4 analoge Anion. Hinsichtlich der Eigendissoziation besteht allerdings ein sehr groer gradueller Unterschied, denn flssiges Ammoniak ist in viel geringerem Mae dissoziiert als Wasser. Die Ionenprodukte und -33 -14 unterscheiden sich um viele Grenordnungen: P = 10 ,P = 110 NH3 H20 Demgem ist die Ammonolyse viel geringer als die Hydrolyse, wenn ein und derselbe Stoff einmal in flssigem Ammoniak das anderemal in wssriger Lsung betrachtet wird.

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