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Eisengruppe: Elemente der achten Nebengruppe

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Springer Nature
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N/A
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GTIN
9783658155612
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Hermann Sicius stellt ausfhrlich die Elemente der achten Nebengruppe (Eisen, Ruthenium, Osmium und Hassium) vor, die allesamt harte, hochschmelzende Metalle sind. Auch bei den Platinmetallen Ruthenium und Osmium wirkt sich noch die Lanthanoidenkontraktion aus. In ihren physikalischen Eigenschaften unterscheiden sich Ruthenium und Osmium relativ deutlich, aber nur wenig in Bezug auf ihre chemischen Eigenschaften. Eisen weicht dagegen hinsichtlich seines unedlen Charakters und niedrigeren Dichten, Schmelz- und Siedepunkten schon deutlich ab. Die Elemente dieser Gruppe knnen maximal acht uere Valenzelektronen abgeben, um eine stabile Elektronenkonfiguration zu erreichen. Die Entdeckung des Eisens eines der hufigsten Elemente berhaupt erfolgte schon 3.000 v. Chr. in Mesopotamien, wogegen Osmium und Ruthenium als sehr seltene Elemente in der ersten Hlfte des 19. Jahrhunderts entdeckt wurden. Die knstliche Erstdarstellung von Atomen des Hassiums gelang 1984.

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