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Cobaltgruppe: Elemente der neunten Nebengruppe

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Product Details

Brand
Springer Nature
Manufacturer
N/A
Part Number
0
GTIN
9783658163457
Condition
New
Product Description

Hermann Sicius stellt ausfhrlich die Elemente der neunten Nebengruppe (Cobalt, Rhodium, Iridium und Meitnerium) vor, deren physikalische und chemische Eigenschaften relativ hnlich sind. Cobalt wurde 1735 entdeckt, Rhodium und Iridium Anfang des 19. Jahrhunderts. Auch beim Elementenpaar Rhodium und Iridium ist noch die Auswirkung der Lanthanoidenkontraktion zu beobachten. Die jeweiligen physikalischen Eigenschaften dieser zwei Elemente unterscheiden sich jedoch schon merklich, nicht aber die chemischen. Die Eigenschaften des Cobalts dagegen weichen von denen der zwei edlen Platinmetalle Rhodium und Iridium deutlich ab, so zeigt Cobalt ein negatives Normalpotential sowie niedrigere Dichten, Schmelz- und Siedepunkte. Bei Cobalt ist aber die Oxidationsstufe +2 die stabilste, bei Rhodium +3 und bei Iridium +4. Krzlich gelang jedoch die Erzeugung von Iridium-VIII- und IX-Verbindungen. 1982 konnten die ersten Atome des Meitneriums erzeugt werden.

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