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Gruppentransferpolymerisation von Michael-Monomeren

Gruppentransferpolymerisation von Michael-Monomeren

Brand
Springer Nature
Manufacturer
N/A
Part Number
0
GTIN
9783658135737
Condition
New
Product Description

Friederike Adams untersucht 2-Aminoalkoxybis(phenolat)-Lanthanoid-Komplexe in der Seltenerdmetall-katalysierten Gruppentransferpolymerisation von Michael-Monomeren. Neu entwickelte C1-symmetrische Komplexe sind dabei in der Lage, isospezifisch 2-Vinylpyridin zu polymerisieren. Mechanistische Studien ber 13C-NMR-Spektroskopie zeigen, dass die Katalysatorumgebung dabei stereoregulierend wirkt. Die Autorin fhrt auerdem erfolgreich Studien zur C-H-Bindungsaktivierung von Heteroaromaten via -Bindungsmetathese durch, um effizientere Initiatoren in diese Systeme einzufhren.

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