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Polymerdekorierte Tensid-Doppelschichten

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Brand
Springer Nature
Manufacturer
N/A
Part Number
0
GTIN
9783658240431
Condition
New
Product Description

In dieser Arbeit wird der Einfluss von polymeren Gastmoleklen auf die Eigenschaften der Selbstaggregation in binren Systemen Wasser - nichtionisches Tensid und insbesondere auf Tensid-Doppelschichten als Modelle fr biologische Membranen untersucht. Durch die Zugabe kleiner Mengen Stickerpolymere dehnen sich diese verdnnten lamellaren La- und L3-Phasen bis zu ultra-niedrigen Konzentrationen aus oder werden sogar induziert. SANS-, SAXS- sowie Lichtstreu-Experimente und die Analyse der Streudaten mittels vorgegebener Strukturmodelle und der modellfreien generalisierten indirekten Fourier Transformation lieferten CAILL-Parameter, Dicke und Abstand der Doppelschichten. Letzterer verringert sich durch die Abnahme der Undulationen und eine mit zunehmendem Polymeranteil steigende Biegesteifigkeit des polymerdekorierten Bilayers. Dieser Effekt des Polymers hngt nicht nur von der Oberflchenbedeckung ab, sondern auch von der Gre des hydrophilen Polymer-Blocks. NSE-Untersuchungen belegen eine durch das Polymer bedingte Verlangsamung der Membrandynamik.

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