Studies on Green Synthetic Reactions Based on Formic Acid from Biomass

Name: Studies on Green Synthetic Reactions Based on Formic Acid from Biomass
Brand: Springer Nature
SKU: 9789811576225
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Springer Nature

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9789811576225

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This book introduces readers to the use of formic acid for efficient organic synthesis. It describes the N-methylation of aromatic and aliphatic amines with formic acid using a boron-based catalyst [B(C6F5)3] in combination with silanes and without the need for an expensive transition metal catalyst. It also shows that formic acid interacts with alkynes and allyl alcohols through a carbonylation process that generates carbon monoxide in situ from nickel and palladium catalysis, respectively, doing away with the need to use high-pressure CO gas and offering a user-friendly and practical method for preparing functionalized , - and , -unsaturated carboxylic acids. The findings presented not only enrich the field of C1 chemistry, but also support the advancement of green and sustainable chemistry.

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